Ring selectivity and migratory aptitude of Cp*Ru+ complexation to acecorannulene

Literature Information

Publication Date 2004-03-12
DOI 10.1039/B316061K
Impact Factor 6.222
Authors

T. Jon Seiders, Joseph M. O'Connor


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Abstract

Synthesis and spectral characterization of acecorannulene CpRu+ complexes, in combination with ab initio quantum chemical computations, leads to the hypothesis that η6-metal binding prefers the exo face in the region of least curvature.

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