A three-dimensional cross-linking supramolecular polymer stabilized by the cooperative dimerization of the viologen radical cation
Literature Information
Publication Date
2013-09-09
DOI
10.1039/C3PY01006F
Impact Factor
5.582
Authors
Cen Zhou, Jia Tian, Ji-Liang Wang, Dan-Wei Zhang, Xin Zhao, Yi Liu, Zhan-Ting Li
View Original
Abstract
Simply introducing four viologen units to a tetraphenylmethane framework causes the corresponding viologen radical cation to strongly dimerize intermolecularly, with the apparent equilibrium constant being increased by at least 7600 times, which drives the tetrahedral molecule to self-assemble into a three-dimensional (3D) supramolecular architecture in water.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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