Unexpected features of stretched Si–H⋯Mo β-agostic interactions‡
Literature Information
Stanislav K. Ignatov, Nicholas H. Rees, Stuart R. Dubberley, Alexei G. Razuvaev, Philip Mountford, Georgii I. Nikonov
Coupling of silanes with the imido group of (Ar′N)2Mo(PMe3)3 gives either the silanimine dimer (ArN–SiHCl)2 or Si–H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si–H addition and the value of the Si–H coupling constant.
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![1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure 1,10-bis(3,5-dimethylphenyl)-12-hydroxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine 12-oxide structure](https://static.chemtradehub.com/structs/141/1412439-82-7-b9a9.webp)


