Unexpected features of stretched Si–H⋯Mo β-agostic interactions‡

Literature Information

Publication Date 2004-03-10
DOI 10.1039/B315517J
Impact Factor 6.222
Authors

Stanislav K. Ignatov, Nicholas H. Rees, Stuart R. Dubberley, Alexei G. Razuvaev, Philip Mountford, Georgii I. Nikonov


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Abstract

Coupling of silanes with the imido group of (Ar′N)2Mo(PMe3)3 gives either the silanimine dimer (ArN–SiHCl)2 or Si–H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si–H addition and the value of the Si–H coupling constant.

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