Kinetics of the interaction of water vapour with mineral dust and soot surfaces at T = 298 K
Literature Information
Sabine Seisel, Yu Lian, Thorsten Keil, Maxim E. Trukhin, Reinhard Zellner
The interaction of water vapour with mineral dust and soot surfaces has been studied at T = 298 K using a Knudsen cell reactor. For the uptake of water vapour on mineral dust an adsorption constant of kads = 6.0 ± 1.1 s−1, corresponding to an uptake coefficient of γini = (4.2 ± 0.7) × 10−2 has been determined. The uptake has been found to be reversible and a desorption rate constant of kdes = (1.7 ± 0.1) × 10−3 s−1 has been determined. For the uptake of water vapour on soot an uptake coefficient of γini = (3.6 ± 2.0) × 10−4 has been determined. However, in this case the uptake was found to be more complex with reversible adsorption and rapid saturation of surface sites simultaneously taking place. In order to separate the adsorption and desorption process, additional experiments using D2O as gaseous reactant have been performed.
Related Literature
Azodicarboxylate-free esterification with triphenylphosphine mediated by flavin and visible light: method development and stereoselectivity control
Michal März, Michal Kohout, Tomáš Neveselý, Josef Chudoba, Dorota Prukała, Stanislaw Niziński, Marek Sikorski, Gotard Burdziński, Radek Cibulka
DOI: 10.1039/C8OB01822G
Cross coupling reactions of organozinc iodides with solid-supported electrophiles: synthesis of 4-substituted benzoic and 3-substituted (E)- and (Z)-propenoic acids and amides
Leslie J. Oates, Richard F. W. Jackson, Michael H. Block
DOI: 10.1039/B208632H
A stereodivergent, two-directional synthesis of stereoisomeric C-linked disaccharide mimetics
Michael Harding, Robert Hodgson, Tahir Majid, Kenneth J. McDowall
DOI: 10.1039/B208781B
First enantioselective total synthesis of altersolanol A
Bastian Mechsner
DOI: 10.1039/C8OB02113A
Azlactone-based heterobifunctional linkers with orthogonal clickable groups: efficient tools for bioconjugation with complete atom economy
Hien The Ho, Alexandre Bénard, Gwenaël Forcher, Maël Le Bohec, Véronique Montembault, Sagrario Pascual, Laurent Fontaine
DOI: 10.1039/C8OB01807C
Refined methods for the synthesis of meso-substituted A3- and trans-A2B-corroles
Daniel T. Gryko, Beata Koszarna
DOI: 10.1039/B208950E
Total synthesis of (±)-rhazinal, an alkaloidal spindle toxin from Kopsia teoi
Martin G. Banwell, Alison J. Edwards, Jason A. Smith, Ernest Hamel, Pascal Verdier-Pinard
DOI: 10.1039/B209992F
One-pot synthesis of natural-product inspired spiroindolines with anti-cancer activities
Shi-Qiang Li, Liu-Jun He, Ming Zhang, Dian-Yong Tang, Hong-yu Li, Zhong-Zhu Chen, Zhi-Gang Xu
DOI: 10.1039/D1QO01694F
Formal reductive addition of acetonitrile to aldehydes and ketones‡
Karim Muratov, Ekaterina Kuchuk, Sreekumar Vellalath, Oleg I. Afanasyev, Alexei P. Moskovets, Gleb Denisov, Denis Chusov
DOI: 10.1039/C8OB01992D
Synthesis of difluoromethylated enynes by the reaction of α-(trifluoromethyl)styrenes with terminal alkynes
Mingsheng Wu, Xianghu Zhao, Yisen Liu, Song Cao
DOI: 10.1039/C8OB02117A
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![[4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure [4-Chloro-3-(diethylcarbamoyl)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/871/871332-68-2-0e3b.webp)



