Synthesis of methanesulfonyl chloride (MSC) from methane and sulfuryl chloride

Literature Information

Publication Date 2004-01-27
DOI 10.1039/B314160H
Impact Factor 6.222
Authors

Sudip Mukhopadhyay, Mark Zerella, Alexis T. Bell, R. Vijay Srinivas, Gary S. Smith


View Original

Abstract

Methane is transformed selectively to methanesulfonyl chloride at low temperature by liquid-phase reaction of methane with SO2Cl2 in the presence of a free radical initiator and a promoter using 100% H2SO4 as the solvent.

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