Reactions of N-heterocyclic carbenes (NHCs) with one-electron oxidants: possible formation of a carbenecation radical

Literature Information

Publication Date 2004-04-01
DOI 10.1039/B314110A
Impact Factor 6.222
Authors

Taramatee Ramnial, Iain McKenzie, Brian Gorodetsky, Emily M. W. Tsang, Jason A. C. Clyburne


View Original

Abstract

One-electron oxidation of N-heterocyclic carbenes (NHCs) has been carried out using oxidising agents such as tetracyanoethylene (TCNE) and ferrocenium [Cp2Fe]+; the formation of carbene radical cations is postulated.

Related Literature

Synthetic approaches for copolymers containing nucleic acids and analogues: challenges and opportunities

Hao Lu, Jiansong Cai, Ke Zhang

2021-03-29 Review Article

DOI: 10.1039/D0PY01707H

Purpurin derivatives as visible-light photosensitizers for 3D printing and valuable biological applications

Pauline Sautrot-Ba, Vlasta Brezová, Jean-Pierre Malval, Annalisa Chiappone, Louise Breloy, Samir Abbad-Andaloussi, Davy-Louis Versace

2021-03-24 Paper

DOI: 10.1039/D1PY00126D

Front cover

2021-04-27 Cover

DOI: 10.1039/D1PY90059E

Well-defined hydrogen and organofunctional polysiloxanes with spiro-fused siloxane backbones

Takahiro Kawatsu, Keita Fuchise, Katsuhiko Takeuchi, Jun-Chul Choi, Kazuhiko Sato, Kazuhiro Matsumoto

2021-03-18 Paper

DOI: 10.1039/D0PY01503B

Mediating covalent crosslinking of single-chain nanoparticles through solvophobicity in organic solvents

Georg M. Scheutz, Justine Elgoyhen, Kyle C. Bentz, Hao Sun, Junpeng Zhao, Daniel A. Savin, Brent S. Sumerlin

2021-07-27 Communication

DOI: 10.1039/D1PY00780G

Structural design of pyrene-functionalized TEMPO-containing polymers for enhanced electrochemical storage performance

Hatice Mutlu, Hongjiao Li, Wolfgang Wenzel

2021-04-06 Paper

DOI: 10.1039/D0PY01421D

Back cover

2021-04-06 Cover

DOI: 10.1039/D1PY90050A

Correlations of nanoscale film morphologies and topological confinement of three-armed cage block copolymers

Brian J. Ree, Yusuke Satoh, Takuya Isono, Toshifumi Satoh

2021-05-25 Paper

DOI: 10.1039/D1PY00421B

You might also like

Compound Q&A

What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?

When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...

16712-20-2Lithium chloride hyd...
Compound Q&A

Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?

4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...

690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A

How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?

Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...

16733-85-01,3-Thiazole-2-carbo...
Compound Q&A

What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?

5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...

934175-58-35-(Difluoromethyl)-2...
Compound Q&A

How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?

Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...

22288-79-5Methyl 3-acetamido-2...
Compound Q&A

What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?

4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...

34846-65-64-Isoquinolinecarbon...
Compound Q&A

How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?

Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...

877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A

What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?

6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...

1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A

Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?

(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...

23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A

What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?

7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....

1293987-84-47-bromo-3-methyl-3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.