Mediating covalent crosslinking of single-chain nanoparticles through solvophobicity in organic solvents
Literature Information
Georg M. Scheutz, Justine Elgoyhen, Kyle C. Bentz, Hao Sun, Junpeng Zhao, Daniel A. Savin, Brent S. Sumerlin
We describe the photoinduced intrachain crosslinking of coumarin-containing copolymers in various organic solvents. Analysis of copolymer solvation and comparison to a molecular coumarin derivative revealed solvophobicity-driven crosslinking kinetics and chain compaction that facilitated the synthesis of single-chain nanoparticles.
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