Highly diastereoselective formation of C2-symmetric bis-thioglycoside Pd(ii) complexes: the role of the exo anomeric effect

Literature Information

Publication Date 2004-02-16
DOI 10.1039/B313798H
Impact Factor 6.222
Authors

Noureddine Khiar, Cristina S. Araújo, Bélen Suárez, Eleuterio Alvarez, Inmaculada Fernández


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Abstract

Treatment of several C2 symmetric bis-thioglycosides with Pd(CH3CN)2Cl2 always leads to a single diastereomeric Pd(II) complex as a consequence of the exo-anomeric effect.

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