A cationic 24-MC-8 manganese cluster with ring metals possessing three oxidation states [MnII4MnIII6MnIV2(μ4-O)2(μ3-O)4(μ3-OH)4(μ3-OCH3)2(pko)12](OH)(ClO4)3‡
Literature Information
Publication Date
2003-09-30
DOI
10.1039/B309439A
Impact Factor
6.222
Authors
Catherine Dendrinou-Samara, Curtis M. Zaleski, Andri Evagorou, Jeff W. Kampf, Vincent L. Pecoraro, Dimitris P. Kessissoglou
View Original
Abstract
Reaction of Mn(ClO4)2 with di-pyridyl ketone oxime, (2-py)2CNOH, gives the novel cluster [MnII4MnIII6MnIV2(μ4-O)2(μ3-O)4(μ3-OH)4(μ3-OCH3)2(pko)12](OH)(ClO4)3 1. It is the only example of a 24-MC-8, and the first metallacrown with ring metal ions in three different oxidation states. Magnetic measurements show antiferromagnetic behavior.
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Source Journal
Chemical Communications
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Recommended Compounds
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N-{15-[(2,5-Dioxo-1-pyrrolidinyl)oxy]-15-oxo-3,6,9,12-tetraoxapentadec-1-yl}-2-(2-propyn-1-yloxy)acetamide
CAS Number:
2101206-92-0
Molecular Formula:
C20H30N2O10
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