Synthesis and characterization of luminescent osmium(ii) carbonyl complexes based on chelating dibenzoylmethanate and halide ligands
Literature Information
Yao-Lun Chen, Chittaranjan Sinha, I-Chia Chen, Kuan-Lin Liu, Yun Chi, Jen-Kan Yu, Pi-Tai Chou, Tian-Huey Lu
Octahedral Os(II) complexes 1–5 with formula [Os(CO)3X(dbm)] are prepared through utilization of both solid-state pyrolysis and ligand exchange reactions. These complexes exhibit prominent 3π–π* phosphorescence with unusually long lifetimes (29–64 µs) and high quantum yields (0.08–0.13).
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