[V(η5-C5H5)]2C8H6: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

Literature Information

Publication Date 2003-07-29
DOI 10.1039/B306688F
Impact Factor 6.222
Authors

Simon C. Jones, Dermot O'Hare


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Abstract

The bimetallic complex [V(Cp)]2Pn, containing a V–V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

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