Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide
Literature Information
Publication Date
2003-06-02
DOI
10.1039/B304633H
Impact Factor
6.222
Authors
Falguni Basuli, Brad C. Bailey, John C. Huffman, Daniel J. Mindiola
View Original
Abstract
One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)2 (Nacnac− = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)2C6H3) with AgOTf affords the cation [(Nacnac)Ti(NHAr)2][OTf] which is isolated and shown to gradually transform, by α-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac)TiNAr(OTf).
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