Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

Literature Information

Publication Date 2003-06-02
DOI 10.1039/B304633H
Impact Factor 6.222
Authors

Falguni Basuli, Brad C. Bailey, John C. Huffman, Daniel J. Mindiola


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Abstract

One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)2 (Nacnac− = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)2C6H3) with AgOTf affords the cation [(Nacnac)Ti(NHAr)2][OTf] which is isolated and shown to gradually transform, by α-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac)TiNAr(OTf).

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