Calamitic and discotic mesophases formed by kinetically controlled rod–disc alternation of molecular shape in a triphenylene–azobenzene mesogenic system
Literature Information
Yo Shimizu, Atsuhiko Kurobe, Hirosato Monobe, Naohiro Terasawa, Kenji Kiyohara, Kingo Uchida
A triphenylene mesogen with the peripheral azobenzene units was found to show kinetically controlled bimesomorphism, with a metastable smectic and a stable hexagonal columnar (Colh) phases on cooling, which is caused by the rod–disc alternation of the molecular shape.
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