Hydrotelluration of aminoalkynes

Literature Information

Publication Date 2003-04-28
DOI 10.1039/B301857A
Impact Factor 6.222
Authors

Gilson Zeni, Olga Soares do Rego Barros, Angélica Venturini Moro, Antonio Luiz Braga, Clovis Peppe


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Abstract

Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the amino group substituent.

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