Synthesis of ionisable [2 × 2] grid-type metallo-arrays and reversible protonic modulation of the optical properties of the [Co II4L4]8+ species
Literature Information
Jean-Marie Lehn, Gavin Vaughan
The new bis-hydrazone based ligands A and B form ionisable [2 × 2] grid-type transition metal complexes whose properties may be modulated by multiple protonation/deprotonation as shown by the reversible change in optical properties of the [CoII4L4]8+ complexes depending on their protonation state.
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![4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure 4,4-Difluoro-2-methyl-1-{[(2-methyl-2-propanyl)oxy]carbonyl}-L-proline structure](https://static.chemtradehub.com/structs/119/1194032-23-9-f426.webp)