Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex

Literature Information

Publication Date 2003-05-21
DOI 10.1039/B303852A
Impact Factor 6.222
Authors

Hiroto Yoshida, Yasuhito Yamaryo, Joji Ohshita, Atsutaka Kunai


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Abstract

Oxidative homocoupling reaction of aryl- or alkynylsilanes was found to proceed without any added activators using a catalytic amount of a palladium–1,3-bis(diphenylphosphino)propane complex, affording the corresponding biaryls or 1,3-diynes in modest to excellent yields.

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