Activator-free oxidative homocoupling of organosilanes catalysed by a palladium–DPPP complex
Literature Information
Hiroto Yoshida, Yasuhito Yamaryo, Joji Ohshita, Atsutaka Kunai
Oxidative homocoupling reaction of aryl- or alkynylsilanes was found to proceed without any added activators using a catalytic amount of a palladium–1,3-bis(diphenylphosphino)propane complex, affording the corresponding biaryls or 1,3-diynes in modest to excellent yields.
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