Rotationally resolved reaction product imaging using crossed molecular beams

Literature Information

Publication Date 2003-05-14
DOI 10.1039/B303166G
Impact Factor 3.676
Authors

Rachel L. Toomes


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Abstract

The hydrogen abstraction reactions of atomic chlorine with ethane and n-butane are studied in a skimmerless crossed molecular beam experiment by imaging of state-selected products. The differential cross section for HCl(v = 0, J = 1–5) product is directly determined from the product velocity map image. The state selection of products is achieved using (2 + 1) resonance enhanced multiphoton ionization, a method generally not used in crossed-molecular beam experiments due to sensitivity problems. This technique opens the way for a plethora of polyatomic reactions (involving more than three atoms) to be studied with scattering angle and rotational resolution.

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Contents list

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DOI: 10.1039/C3CP90045B

Front cover

Cover

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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