The first example of direct oxidation of sulfides to sulfones by an osmate molecular oxygen system
Literature Information
Boyapati M. Choudary, Chinta Reddy V. Reddy, Billakanti V. Prakash, Mannepalli L. Kantam, B. Sreedhar
Osmate-exchanged Mg–Al layered double hydroxides catalysed the delivery of two oxygen atoms simultaneously via a 3 + 1 cycloaddition to sulfide to form sulfone directly for the first time, reminiscent of 3 + 2 cycloaddition in asymmetric dihydroxylation reactions.
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![1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure 1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure](https://static.chemtradehub.com/structs/57-/57-96-5-efcc.webp)