A ruthenium catalyst that does not require an N–H ligand to achieve high enantioselectivity for hydrogenation of an alkyl-aryl ketone

Literature Information

Publication Date 2003-02-25
DOI 10.1039/B212544G
Impact Factor 6.222
Authors

Carolyn G. Leong, Okwado M. Akotsi, Michael J. Ferguson, Steven H. Bergens


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Abstract

Ruthenium catalysts of the form trans-RuCl2((R)-(S)-Josiphos)L2 where L2 = pyridine or 1,2-diamine, have been synthesized that display high catalytic activity towards the hydrogenation of 1′-acetonaphthone.

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