Novel heteroleptic cis-(C⁁N)2Pd(ii) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine
Literature Information
Publication Date
2003-02-11
DOI
10.1039/B211873D
Impact Factor
6.222
Authors
Alexsandro Berger, Jean-Pierre Djukic, Michel Pfeffer, André de Cian, Nathalie Kyritsakas-Gruber, Jérôme Lacour, Laurent Vial
View Original
Abstract
In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(η6-phenyl)tricarbonylchromium]pyridine with μ-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C⁁N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (η6-arene)Cr(CO)3 complexes.
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Source Journal
Chemical Communications
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Recommended Compounds
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5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one
CAS Number:
1914963-20-4
Molecular Formula:
C25H24O5
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