Novel heteroleptic cis-(C⁁N)2Pd(ii) chelates for the preparation of enantiopure planar chiral cyclopalladated 2-[tricarbonyl(η6-phenyl)chromium]pyridine
Literature Information
Alexsandro Berger, Jean-Pierre Djukic, Michel Pfeffer, André de Cian, Nathalie Kyritsakas-Gruber, Jérôme Lacour, Laurent Vial
In the presence of large amounts of [Me4N]Cl, the reaction of ortho-chloromercurated 2-[(η6-phenyl)tricarbonylchromium]pyridine with μ-chloro cyclopalladated aromatic compounds yields a series of new heteroleptic heterodinuclear cis-(C⁁N)2Pd(II) complexes, which are valuable precursors of planar chiral cyclopalladated (η6-arene)Cr(CO)3 complexes.
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