A novel role of zeolite NaY in the thermal reaction of alkyl aryl selenoxides in its supercages

Literature Information

Publication Date 2003-01-23
DOI 10.1039/B211833E
Impact Factor 6.222
Authors

Haitao Yu, Yu Gao, Jiben Meng, Teruo Matsuura


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Abstract

Thermal reaction of alkyl aryl selenoxides in the presence of water or methanol in the supercage of zeolite NaY gave β-hydroxy- or β-methoxyalkyl aryl selenides, respectively, and NaY played a novel role to stabilize reactive ArSeOH and to separate an anion of −OH from a carbonium ion which was simultaneously present with the −OH in a supercage.

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