Tetranuclear nickel(ii) complexes with genuine μ3-1,1,3 and μ4-1,1,3,3 azide bridges
Literature Information
Franc Meyer, Peter Kircher, Hans Pritzkow
Unique tetranickel(II) complexes have been synthesized which incorporate genuine μ3-1,1,3 or μ4-1,1,3,3 bridging azido ligands. Identification of two distinct isomeric μ4-1,1,3,3 binding modes confirms the structural flexibility of the quadruply bridging azide.
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