Tetranuclear nickel(ii) complexes with genuine μ3-1,1,3 and μ4-1,1,3,3 azide bridges

Literature Information

Publication Date 2003-02-25
DOI 10.1039/B211486K
Impact Factor 6.222
Authors

Franc Meyer, Peter Kircher, Hans Pritzkow


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Abstract

Unique tetranickel(II) complexes have been synthesized which incorporate genuine μ3-1,1,3 or μ4-1,1,3,3 bridging azido ligands. Identification of two distinct isomeric μ4-1,1,3,3 binding modes confirms the structural flexibility of the quadruply bridging azide.

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