A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(i,ii) units

Literature Information

Publication Date 2003-01-15
DOI 10.1039/B210914J
Impact Factor 6.222
Authors

Katsunori Mochizuki, Ho-Chol Chang, Xiao-Ming Chen, Ying Li, Susumu Kitagawa


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Abstract

A novel three-dimensional coordination polymer with a mixed-valence localized copper(I,II) dimeric unit, [Cu2(4-pya)3]n (4-pya = 4-pyridinecarboxylate), was hydrothermally synthesized via a simultaneous in-situa redox and hydrolysis reaction of Cu(II) and 4-cyanopyridine and crystallographically characterized to be a twofold interpenetrated three-dimensional coordination network with a cubic [Cu16(4-pya)12] building unit.

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