A potassium selective ‘nanosponge’ with well defined pores‡

Literature Information

Publication Date 2002-11-18
DOI 10.1039/B210523N
Impact Factor 6.222
Authors

Achim Müller, Bogdan Botar, Hartmut Bögge, Paul Kögerler, Alois Berkle


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Abstract

The novel spherical cluster-compound K2Na6[K20⊂Mo80V22O282(SO4)12(H2O)66]·≈140H2O 1 has been obtained in a ‘one-pot’ reaction and exhibits several remarkable structural features: 30 open shell centers, i.e. 8 MoV and 22 VIV spanning an icosidodecahedron, the incorporation of 20 K+ cations capping 20 appropriate {M6O6} pores/rings present at the surface of the spherical cluster-anion, and an encapsulated aggregate of water molecules.

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