A novel layered oxysulfide intergrowth compound Sr4Mn2Cu5O4S5 containing a fragment of the α-Cu2S antifluorite structure

Literature Information

Publication Date 2002-12-02
DOI 10.1039/B209747H
Impact Factor 6.222
Authors

Nicolas Barrier, Simon J. Clarke


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Abstract

Sr4Mn2Cu5O4S5 contains manganese oxide sheets separated by unusual antifluorite-type Cu3S3 layers in which copper(I) ions are distributed over three- and four-coordinate sites in a similar fashion to in α-Cu2−xS and suggestive of high two-dimensional copper ion mobility.

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