Novel coordination of dicyanamide, [N(CN)2]−: preferential binding of the amidenitrogen

Literature Information

Publication Date 2002-11-06
DOI 10.1039/B208872J
Impact Factor 6.222
Authors

Shireen R. Marshall, Christopher D. Incarvito, William W. Shum, Arnold L. Rheingold, Joel S. Miller


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Abstract

CoII[N(CN)2]2(H2BiIm)2, 1, and {CoII[N(CN)2](H2BiIm)2}Cl, 2 (H2BiIm = 2,2′-biimidazole) have been structurally, spectroscopically, and magnetically characterized with both containing dicyanamides bound in unprecedented manners; namely, solely via the amide nitrogen for 1, and via an imide N forming 1-D helical chains for 2.

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