![(3R,4aR,7aS,9aR,10S,11R,13aR,13bS,15aS,15bR)-3,11-Dihydroxy-10-(hydroxymethyl)-4,4,7a,10,13a,15b-hexamethyl-1,2,3,4,4a,7,7a,8,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-5H-naphtho[2',1':4,5]cyc
lohepta[1,2-a]naphthalen-5-one structure](https://static.chemtradehub.com/structs/538/53800-21-8-9f18.webp "(3R,4aR,7aS,9aR,10S,11R,13aR,13bS,15aS,15bR)-3,11-Dihydroxy-10-(hydroxymethyl)-4,4,7a,10,13a,15b-hexamethyl-1,2,3,4,4a,7,7a,8,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-5H-naphtho[2',1':4,5]cyc
lohepta[1,2-a]naphthalen-5-one structure")
Routes to fluorinated organic derivatives by nickel mediated C–F activation of heteroaromatics
Literature Information
Publication Date
2002-10-11
DOI
10.1039/B206154F
Impact Factor
6.222
Authors
Robin N. Perutz
View Original
Abstract
New fluorinated azaheterocycles can be synthesised regio- and chemo-selectively via C–F activation of fluorinated precursors at nickel, with subsequent functionalisation and release from the coordination sphere of the metal; the requirements for productive C–F activation are significantly different from those for C–H bond activation.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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