Oscillatory clusters in a reaction–diffusion system switching between excitable and unexcitable states

Literature Information

Publication Date 2002-03-13
DOI 10.1039/B109391F
Impact Factor 3.676
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Abstract

In this study, we report the observation of oscillatory clusters in the photosensitive Belousov–Zhabotinsky reaction switching between excitable and unexcitable states. Numerical studies with a three-variable Oregonator model have been carried out in one- and two-dimensional media. Both non-flux and periodic boundaries have been characterized. Two- and three-phase clusters with standing, breathing, and irregular segregations are achieved when the intensity and durations of the two phases of the square-wave forcing are varied. The occurrence of oscillatory clusters in the excitable medium is due to the dual functions of the inhibitory light perturbation, i.e. eliminating existing wave activity as observed in earlier studies and initiating pattern formation at unexcited regions. The unusual positive impact of the inhibitory perturbation is analyzed, based on the flow trajectories of the system in a two-dimensional concentration phase plane.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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