Description of electrolyte effects on the kinetics of reactions between ions in solution, using the mean spherical approximation

Literature Information

Publication Date 2001-09-17
DOI 10.1039/B104407A
Impact Factor 3.676
Authors

Jean-Pierre Simonin, Hendrawan Hendrawan


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Abstract

The effect of an inert salt on the kinetics of solution reactions between ions is examined in the framework of the mean spherical approximation (MSA) theory. The latter is applied to describe activation- and diffusion-controlled reactions in moderately concentrated electrolyte solutions. The results are compared with those obtained using the Debye–Hückel theory, in particular beyond the limit of applicability of this model. It is shown that both theories may be applied to represent salt effects with nearly equal accuracy.

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Indexes

Paper

DOI: 10.1039/CS9841300489

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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