Redox behavior of biferrocene dithiol and disulfide derivatives in SAMs with and without gold clusters on the gold substrate
Literature Information
Yi Men, Kenya Kubo, Masato Kurihara, Hiroshi Nishihara
1′,1‴-(8,8′-Dithiodioctanoyl)-1,1″-biferrocene (Bfc′S2) and 1′,1‴-bis(8-mercaptooctanoyl)-1,1″-biferrocene (Bfc′(SH)2) were synthesized for the purpose of constructing self-assembled monolayers (SAMs) on the gold electrode. These SAMs manifested different structures. The former molecule adsorbed onto the substrate by anchoring its two ends. In contrast, the latter was fixed by only one end, and the other, surplus end was used to anchor the gold cluster to give a SAM with gold clusters. The electrochemical properties of these SAMs were characterized by cyclic voltammetry, which suggested a difference of electronic transference among them. STM images confirmed the array of gold clusters on the surface of the Bfc′(SH)2-modified gold electrode.
Related Literature
Optical-electrical-thermal optimization of plasmon-enhanced perovskite solar cells
Hao Ren, Kaikun Niu, Siliang Wang, Zhixiang Huang, Xianliang Wu
DOI: 10.1039/D0CP02220A
Excited-state non-radiative decay in stilbenoid compounds: an ab initio quantum-chemistry study on size and substituent effects
Sangyoon Oh, Soo Young Park, Johannes Gierschner, Daniel Roca-Sanjuán
DOI: 10.1039/C9CP03308D
PtSe2/SiH van der Waals type-II heterostructure: a high efficiency photocatalyst for water splitting
Shuaicheng Han, Yuee Li, Zhong Wang
DOI: 10.1039/D0CP02900A
Non-adiabatic quantum dynamics of the electronic quenching OH(A2Σ+) + Kr
Pablo Gamallo, F. Javier Aoiz, Carlo Petrongolo
DOI: 10.1039/D0CP02512G
Molecular dynamics simulation insight into the temperature dependence and healing mechanism of an intrinsic self-healing polyurethane elastomer
Xianling Chen, Jing Zhu, Jun Chen, Haobei Liu, Meng Zhang
DOI: 10.1039/D0CP03013A
Correction: The use of ion-selective membranes to study cation transport in hybrid organic–inorganic perovskites
Emily C. Smith, Christie L. C. Ellis, Hamza Javaid, Blaise G. Arden, D. Venkataraman
DOI: 10.1039/C9CP90245G
Sulfur doped Li1.3Al0.3Ti1.7(PO4)3 solid electrolytes with enhanced ionic conductivity and a reduced activation energy barrier
Mine Kırkbınar
DOI: 10.1039/D0CP03442H
Emergent electronically-controllable local-field-inducer based on a molecular break-junction with magnetic radical
Yong-Chen Xiong, Wang-Huai Zhou, Wei Li, Hai-Ming Huang, Nan Nan, Jun Zhang, Jun-Tao Yang
DOI: 10.1039/C9CP04523F
Examining the degradation of environmentally-daunting per- and poly-fluoroalkyl substances from a fundamental chemical perspective
Antonio H. da S. Filho
DOI: 10.1039/D0CP02445G
You might also like
Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?
When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...
How should (1R,9S,10S,12S,14E,16S,19R,20R,21S,22R)-3,9,21-Trihydroxy-5,10,12,14,16,20,22-heptamethyl-23,24-dioxatetracyclo[17.3.1.1~6,9~.0~2,7~]tetracosa-2,5,7,14-tetraen-4-one (CAS: 183202-73-5) be stored?
This compound should be stored in a cool, dry place away from direct sunlight. I...
How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?
3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...
How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?
5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...
What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?
2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...
What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?
3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...
Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?
Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...
Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?
Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...
What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?
3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...
What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?
When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure 2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://static.chemtradehub.com/structs/567/56718-70-8-f037.webp)


