The effect of mechanical stress on the potential of the Ag/Ag+ electrode
Literature Information
The effect of mechanical stress, σ, on electrode potential, E, was studied under zero current conditions. Silver wires in contact with AgNO3 solutions were exposed to tensile stress and the variation of the potential was measured in a two-electrode cell. The change in the steady state, ΔE, was found to be proportional to σ whereas the time dependence, E(t), could be reasonably described by an exponential function. The ΔE s. σ functions were understood in terms of the electrostatics of the double layer enabling one to evaluate the stress dependence of the potential of zero charge, (∂E0/∂σ) = 25.6 ± 1 μV MPa−1; this experimental value is supported by a theoretical estimation.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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