Transport parameters of LiCl and LiBr in aqueous mixtures with organic solvents of moderate to low permittivities
Literature Information
The electromotive forces (emf) EA and EC of the following concentration cells with transference: respectively (where X=Cl, Br), combined with the emfs EMAX of the corresponding double cell without transference: ∣AgX∣LiX(m2)∣LixHg1-x have been measured at LiX molalities m (m1 fixed and m2 varied, with m2>m1) in 14 solvent mixtures pertaining to the three aqueous–organic solvent systems (acetonitrile+water), (1,4-dioxane+water) and (methanol+water) up to the 0.8 mass fraction of organic component. For all of the cases studied the EAvs. EMAX relation is a curve reaching a straight line asymptotically at low LiX molalities. The resulting ionic transference numbers t of LiX show a type of curvilinear dependence on the mass fraction of the organic component which shows analogies with that of the other alkali halides hitherto studied, but is quite distinct from that of HCl. Such a dependence is also analyzed in terms of solvation parameters and the mechanism of ionic motion, with account being taken of Stokes' law ionic radii.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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