Time-resolved surface differential diffraction study of Ag electrodeposition on Au(111) and the role of surface stress

Literature Information

Publication Date
DOI 10.1039/A904775A
Impact Factor 3.676
Authors


View Original

Abstract

An insitu X-ray diffraction investigation using surface differential diffraction (SDD) was carried out to study the mechanism and kinetics of Ag electrodeposition on Au(111). The effect of the surface stress on SDD measurements employing a thin film electrode has been investigated, which reveals that stress-induced peak shifts can account for some inconsistency in previous SDD results. Potential dynamic and potential step modes of deposition were used and the adlayer spacing of Ag on Au(111) was determined as a function of potential and time, respectively. A structural change in adlayer spacing during Ag electrodeposition on Au(111) was observed in both modes of deposition, which is consistent with a transition from initial adsorption in a mixture of bridge and atop sites to three-fold hollow sites.

Related Literature

On the critical Casimir interaction between anisotropic inclusions on a membrane

Jorge Benet, Fabien Paillusson, Halim Kusumaatmaja

2017-08-25 Paper

DOI: 10.1039/C7CP03874G

Atomic structure of Mg-based metallic glasses from molecular dynamics and neutron diffraction

Anastasia Gulenko, Louis Forto Chungong, Junheng Gao, Iain Todd, Alex C. Hannon, Richard A. Martin

2017-03-03 Paper

DOI: 10.1039/C6CP03261C

Optical properties and magnetic flux-induced electronic band tuning of a T-graphene sheet and nanoribbon

Arka Bandyopadhyay, Atanu Nandy, Arunava Chakrabarti, Debnarayan Jana

2017-07-24 Paper

DOI: 10.1039/C7CP03983B

Underpotential deposition of Cu on Au(111) from neutral chloride containing electrolyte

Hannah Aitchison, Nikolaus Meyerbröker, Tien-Lin Lee, Jörg Zegenhagen, Thomas Potter, Herbert Früchtl, Izabela Cebula, Manfred Buck

2017-08-15 Paper

DOI: 10.1039/C7CP04244B

Controllable decomposition of Ca(BH4)2 for reversible hydrogen storage

D. Rentsch, A. Remhof

2017-02-20 Paper

DOI: 10.1039/C7CP00448F

Extending charge separation lifetime and distance in patterned dye-sensitized SnO2–TiO2 μm-thin films

Valeria Saavedra Becerril, Elin Sundin, Mokhtar Mapar, Maria Abrahamsson

2017-08-10 Paper

DOI: 10.1039/C7CP04486K

Characterization of secondary phosphine oxide ligands on the surface of iridium nanoparticles

Israel Cano, Luis M. Martínez-Prieto, Pier F. Fazzini, Bruno Chaudret, Piet W. N. M. van Leeuwen

2017-07-28 Paper

DOI: 10.1039/C7CP03439C

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.