EPR investigations on europium(II)-doped barium aluminate

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DOI 10.1039/A903385H
Impact Factor 3.676
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Abstract

High frequency EPR spectra of europium(II)-doped BaAl2O4 powder phosphor have been analysed. Spectral simulation was carried out by a Fourier transform Monte Carlo method using an equation derived from the second-order perturbation of the energy levels for S=7/2. It is found that the spectra can best be interpreted in terms of europium(II) ions in two different sites. One quarter of the europium(II) ions are located in a site with a ∣D∣ of 0.345 cm-1, and the remaining europium(II) ions are in a site with a ∣D∣ of 1.08 cm-1. Estimated values of ∣E∣ are equal to 1/3

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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