New equations of state for pure and binary hard-sphere fluids
Literature Information
An equation of state for one-component fluids of hard spheres is proposed. The equation has the form of the Pade′ approximant of the rescaled virial series and uses the first seven virial coefficients. The equation is superior to the Carnahan–Starling, the Erpenbeck–Wood and the Kolafa equations of state. It is shown that its accuracy is almost the same as the precision of recent simulation data. The same general form of the equation is used for binary additive mixtures of hard spheres. The equation utilizes known virial coefficients up to the fifth as functions of the mole fraction and the sphere diameter ratio. Comparisons with Monte Carlo computer simulation data show that the equation is more accurate than the Boublík–Mansoori–Carnahan–Starling–Leland and similar equations of state at fluid packing fractions up to η=0.49. Possible extensions and applications of the proposed equations are discussed.
Recommended Journals

Bioorganic & Medicinal Chemistry Letters

Journal of the Indian Institute of Science

Atomization and Sprays

Bioorganic & Medicinal Chemistry

Critical Reviews in Solid State and Materials Sciences

Acta Metallurgica Sinica-English Letters

Chinese Journal of Chemistry

Colloid Journal

NDT & E International

Heteroatom Chemistry
Related Literature
In situ probing of the crystallization kinetics of rr-P3HT on single layer graphene as a function of temperature
Nicolas Boulanger, Victor Yu, Michael Hilke, Michael F. Toney, David R. Barbero
DOI: 10.1039/C6CP08589J
Coexistence of ice clusters and liquid-like water clusters on the Ru(0001) surface
Feng Liu, J. M. Sturm, Chris J. Lee, Fred Bijkerk
DOI: 10.1039/C6CP07369G
Controllable decomposition of Ca(BH4)2 for reversible hydrogen storage
D. Rentsch, A. Remhof
DOI: 10.1039/C7CP00448F
The electronic properties of three popular high spin complexes [TM(acac)3, TM = Cr, Mn, and Fe] revisited: an experimental and theoretical study
S. Carlotto, L. Floreano, A. Cossaro, M. Rancan, M. Sambi
DOI: 10.1039/C7CP04461E
Modulation of in:out and out:out conformations in [X.X′.X′′] phosphatranes by Lewis acids
Goar Sánchez-Sanz, Cristina Trujillo, Ibon Alkorta, José Elguero
DOI: 10.1039/C7CP03661B
Rare-earth doped fluoride phosphate glasses: structural foundations of their luminescence properties
Marcos de Oliveira, Jr.
DOI: 10.1039/C7CP03927A
Self-thermophoretic motion of controlled assembled micro-/nanomotors
Xiankun Lin, Tieyan Si, Zhiguang Wu, Qiang He
DOI: 10.1039/C7CP02561K
Tunable AIEE fluorescence constructed from a triphenylamine luminogen containing quinoline – application in a reversible and tunable pH sensor
Mengmeng Zhang, Wen Yang, Tingfeng Gong, Weiqun Zhou, Renyu Xue
DOI: 10.1039/C7CP03234J
Ferrocene and ferrocenium inclusion compounds with cucurbiturils: a study of metal atom dynamics probed by Mössbauer spectroscopy
Clara I. R. Magalhães, Ana C. Gomes, André D. Lopes, Isabel S. Gonçalves, Martyn Pillinger, Eunyoung Jin, Ikjin Kim, Young Ho Ko, Israel Nowik, Rolfe H. Herber
DOI: 10.1039/C7CP04416J
A ground state potential energy surface for HONO based on a neural network with exponential fitting functions
Ekadashi Pradhan, Alex Brown
DOI: 10.1039/C7CP04010E
You might also like
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




