The effect of oxygen pressure on the tropospheric oxidation of diethyl ether, H-atom elimination from the 1-ethoxyethoxy radical

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Publication Date
DOI 10.1039/A902243K
Impact Factor 3.676
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Abstract

The simulated tropospheric oxidation of diethyl ether gave yields of the products ethyl formate, acetaldehyde and ethyl acetate in broad agreement with previous studies. However the effect of variation of oxygen pressure on the relative yields of ethyl acetate and ethyl formate disagrees with the prediction of the mechanism previously proposed. It is suggested that ethyl acetate is produced by the reaction C2H5OCH(O)CH3→CH3COOC2H5+H as well as by the reaction of the 1-ethoxyethoxy radical with oxygen.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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