2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] | CAS No. 817176-80-0

2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine]

Basic Information

CAS Number

817176-80-0

Molecular Formula

C45H42P2

Molecular Weight

644.78 g/mol

AD

Basic Physical Properties

Melting Point

154-161 °C

Specific Rotation

-221° (c 0.54, CH2Cl2)

c1ccc(c2c1CCC26c5c(P(c3ccc(cc3)C)c4ccc(cc4)C)cccc5CC6)P(c7ccc(cc7)C)c8ccc(cc8)C

InChI

InChI=1S/C45H42P2/c1-31-11-19-37(20-12-31)46(38-21-13-32(2)14-22-38)41-9-5-7-35-27-29-45(43(35)41)30-28-36-8-6-10-42(44(36)45)47(39-23-15-33(3)16-24-39)40-25-17-34(4)18-26-40/h5-26H,27-30H2,1-4H3

InChIKey

VLIOMJFCGWZUON-UHFFFAOYSA-N

LogP

8.615180000000004

Topological Polar Surface Area

0.0 Ų

Hydrogen Bond Donor/Acceptor

0 / 0

Safety Information

View Safety Information

Sensitiveness

air sensitive

Synonyms & References

English

  • Phosphine,1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-methylphenyl)-
  • Phosphine,1,1'-[(1S)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(4-meth...

MDL Number

MFCD08459345

FAQ

What are the physical and chemical properties of 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 817176-80-0)?

2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] is a solid compound with a crystalline form. It has a high molecular weight and low solubility in water but is soluble in organic solvents. It is known for its high reactivity towards nucleophiles and electrophiles. This compound is widely used in chemical reactions due to its unique structural properties.

How is 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 817176-80-0) typically synthesized?

2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] is typically synthesized through a multistep process involving the coupling of indene derivatives with 4-methylphenylphosphine. The reaction is catalyzed by transition metal complexes, and the yield can be improved by optimizing reaction conditions and using selective catalysts.

What industries use 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 817176-80-0)?

2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] is used in various industries, including pharmaceuticals for catalyst preparation, polymers for functionalization, and sensors for detection of specific chemicals. It is also used in semiconductor fabrication for surface modification and passivation.

What precautions should be taken when handling 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine] (CAS: 817176-80-0)?

When handling 2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diylbis[bis(4-methylphenyl)phosphine], it is important to use personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be conducted in a well-ventilated area or a fume hood. Spills should be cleaned up carefully and in accordance with safety data sheet (SDS) guidelines. Proper storage should be in a cool, dry place away from direct sunlight and flammable materials.

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