L-Selectride Solution (1.0 M in THF)

Basic Information

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CAS Number

38721-52-7

Molecular Formula

C12H27BLi

Molecular Weight

189.1 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Hydrocarbons

Basic Physical Properties

Melting Point

49°C

Boiling Point

203°C

Flash Point

-17 ºC

Solubility

Miscible with tetrahydrofuran.

SMILES

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[Li+].[B-](C(C)CC)(C(C)CC)C(C)CC

InChI

InChI=1S/C12H27B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-12H,7-9H2,1-6H3;/q-1;+1

InChIKey

LXGCMJBNHPPNBQ-UHFFFAOYSA-N

LogP

4.88150

Complexity

104

Safety Information

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GHS Hazard Pictograms

H225

H250

H260

H314

H335

Hazard Statement

H225 Highly Flammable liquid and vapor
Flammable liquids

H250 Catches fire spontaneously if exposed to air
Pyrophoric liquids; Pyrophoric solids

H260 In contact with water releases flammable gases which may ignite spontaneously
Substances And Mixtures Which, In Contact With Water, Emit Flammable Gases

H314 Causes severe skin burns and eye damage
Skin corrosion/irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Hazard Class

Class 4.3 Class 4.3

Sensitiveness

Moisture Sensitive

Synonyms & References

English

Lithium selectride; Lithium tri(s-butyl)borohydride; Lithium tri-sec-butylborohydride; Lithium tri-sec-butylhydroborate(1-); Lithium tris(s-butyl)hydroborate(1-)
LITHIUM TRI-SEC-BUTYLHYDROBORATE(1-)
Lithium tri-sec-butylhydridoborate, 1.0M in THF
Borate(1-), hydrotris(1-methylpropyl)-, lithium (1:1), (T-4)-
UNII-J471N7T23N
LITHIUM HYDROTRI-S-BUTYLBORATE
Lithium tri-sec-butylhydroborate
38721-52-7
Lithium Tri-sec-butylborohydride
L0164
FT-0652836
A824243
LXGCMJBNHPPNBQ-UHFFFAOYSA-N
LITHIUM SELECTRIDE
Borate(1-), hydrotris(1-methylpropyl)-, lithium, (T-4)-
AKOS009113012
BP-13469
L-SELECTRIDE [MI]
lithium tri(butan-2-yl)boron(1-)
J471N7T23N
LITHIUM TRIS(S-BUTYL)HYDROBORATE(1-)
EC 254-101-1
MFCD00011708
Lithium tris(sec-butyl)borohydride
EINECS 254-101-1
lithium tri(s-butyl)borohydride
Lithium tri-sec-butylborohydride
Lithium triisobutylhydroborate
L-selectride
lithium tri-sec-butylhydroborate
Lithiumbutylborohydride

MDL Number

MFCD00011708

Customs Code

29319090

FAQ

What is L-Selectride Solution (1.0 M in THF) (CAS: 38721-52-7)?

L-Selectride Solution (1.0 M in THF) is a chemical compound used primarily in organic synthesis. It is a solution of L-selectride in tetrahydrofuran (THF) at a concentration of 1.0 molar. The chemical formula is [Formula to be provided based on specific compound details]. This solution is known for its reactivity and is often used in reducing functionalities in organic molecules.

What are the main uses of L-Selectride Solution (1.0 M in THF) (CAS: 38721-52-7)?

L-Selectride Solution (1.0 M in THF) is widely used in the pharmaceutical and chemical industries for the selective reduction of aldehydes and ketones to alcohols. It is also utilized in the synthesis of various organic compounds, including chiral molecules, which are important in drug development. Its reactivity makes it a valuable tool for organic chemists.

Is L-Selectride Solution (1.0 M in THF) (CAS: 38721-52-7) safe?

L-Selectride Solution (1.0 M in THF) is classified as hazardous due to its reactivity and potential for decomposition. It should be handled in a well-ventilated fume hood and with appropriate personal protective equipment (PPE), such as gloves and goggles. Storage should be in a cool, dry place away from direct sunlight and incompatible materials. Ensure proper disposal according to local regulations.

How should L-Selectride Solution (1.0 M in THF) (CAS: 38721-52-7) be stored?

L-Selectride Solution (1.0 M in THF) should be stored in a cool, dry place at a temperature no higher than 15°C. Avoid exposure to direct sunlight and protect it from moisture. Use airtight, light-resistant containers to minimize degradation. Store it away from strong acids, bases, and other reactive substances to prevent adverse reactions.