Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese

Basic Information

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CAS Number

32195-55-4

Molecular Formula

C44H28ClMnN4

Molecular Weight

703.13 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Heterocyclic Compounds

Pharmaceutical Chemicals Pharmaceutical Intermediates Heterocyclic Intermediates

Fine Chemicals Dyes and Pigments Organic Dyes

Agricultural Chemicals Pesticides Herbicides

Laboratory Chemicals Research Chemicals Biochemical Reagents

Basic Physical Properties

SMILES

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C1=CC=C(C=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C([N-]5)C(=C6C=CC2=N6)C7=CC=CC=C7)C8=CC=CC=C8)C=C4)C9=CC=CC=C9)[N-]3.[Cl-].[Mn+3]

InChI

InChI=1S/C44H28N4.ClH.Mn/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36;;/h1-28H;1H;/q-2;;+3/p-1/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-;;

InChIKey

MIUMWNDEIWVIEG-YKKPBKTHSA-M

LogP

8.253600000000006

Topological Polar Surface Area

34.58 Å²

Hydrogen Bond Donor/Acceptor

0 / 4

Complexity

807

Safety Information

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Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Synonyms & References

English

32195-55-4
5,10,15,20-Tetraphenyl-21H,23H-porphine manganese(iii) chloride
M2621
manganese(3+);5,10,15,20-tetraphenylporphyrin-22,24-diide;chloride
MFCD00012153
YSWG544
Chloride ionophore I
Manganese(III) Tetraphenylporphyrin Chloride
Manganese(III) 5,10,15,20-(tetraphenyl)porphyrin chloride
manganese(3+);5,10,15,20-tetraphenylporphyrin-22,23-diide;chloride
Manganese,chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-kN21,kN22,kN23,kN24]-, (SP-5-12)-
(5,10,15,20-Tetraphenylporphinato)manganese(III) chloride
5,10,15,20-Tetraphenyl-21H,23H-Porphine Manganese(Iii) Chloride
manganese(3+),10,12,13,23-tetraphenyl-21H-porphyrin,trichloride
(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride
(meso-tetraphenylporphyrinato)chloromanganese(III)
(meso-tetraphenylporphyrinato)magnesium(II)
5,10,15,20-Tetraphenyl-21H,23H-porphine magnesium(II)
5,10,15,20-tetraphenylporphyrinatomanganese(III) chloride
Magnesium meso-te
MAGNESIUM MESO-TETRAPHENYLPORPHYRIN
magnesium tetraphenylporphyrin
manganese(III) meso-tetraphenylporphyrin chloride
TPP-Mn(2+)

MDL Number

MFCD00012153

FAQ

What are the physical and chemical properties of Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4)?

Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4) is a crystalline compound with a molecular weight of approximately 849.4 g/mol. It is poorly soluble in water but soluble in organic solvents like ethanol and chloroform. This compound is highly reactive, particularly towards various metal ions and organic substrates. It is known for its strong absorption in the visible and near-infrared regions, making it useful in photodynamic therapy and sensing applications.

How is Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4) typically synthesized?

Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4) is synthesized using a multi-step process involving the coordination of a chloro-activated tetraphenylporphyrin with manganese(II) chloride in the presence of an organic solvent. Common solvents include methanol and ethanol. This synthesis yields a product with high purity and good selectivity, with a typical yield of about 70%. Proper handling of reagents and solvents is essential to ensure safety and efficiency.

What industries use Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4)?

Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4) is widely used in the pharmaceutical industry for photodynamic therapy, and in the development of sensors for detecting various metal ions. It is also utilized in the semiconductor industry for its unique electronic properties and in polymer applications for its stability and reactivity. Additionally, this compound is of interest in the field of catalysis, particularly in heterogeneous catalysis.

What precautions should be taken when handling Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4)?

When handling Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-kappa~2~N~21~,N~23~]manganese (CAS: 32195-55-4), it is crucial to use personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be conducted in a well-ventilated area or a fume hood. If a spill occurs, it should be cleaned up immediately using appropriate spill kits. Always refer to the safety data sheet (SDS) for detailed handling and disposal information. This compound can be toxic and may cause skin irritation and respiratory issues if not handled properly.