Nickel(2+) bromide - triphenylphosphine (1:2:2)

Basic Information

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CAS Number

14126-37-5

Molecular Formula

C36H30Br2NiP2

Molecular Weight

743.09 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

219-223 °C

Boiling Point

360°C at 760 mmHg

Flash Point

181.7°C

SMILES

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C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni](Br)Br

InChI

InChI=1S/2C18H15P.2BrH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChIKey

QEKXARSPUFVXIX-UHFFFAOYSA-L

LogP

8.578300000000008

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

204

Safety Information

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GHS Hazard Pictograms

H302

H312

H332

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

H332 Harmful if inhaled
Acute toxicity, inhalation

Hazard Class

Class 6.1(b) Class 6.1(b)

Synonyms & References

English

AKOS015904058
SCHEMBL196810
NICKEL(II)BROMIDEBIS(TRIPHENYLPHOSPHINE)
NICKEL(II) BROMIDE BIS(TRIPHENYLPHOSPHINE)
Bis(triphenylphosphine)nickel(II)bromide
DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL
bis(triphenylphosphine)nickel(II) bromide
NiBr2(PPh3)2
Dibromobis(triphenylphosphine)nickel(II), 99%
MFCD00015865
FT-0688273
14126-37-5
dibromonickel;triphenylphosphane
DTXSID40453273
Nickel, dibromobis(triphenylphosphine)- (6CI,7CI,8CI,9CI)
AC-28791
C36H30Br2NiP2
Dibromobis(triphenylphosphine)nickel(II)
BIS(TRIPHENYLPHOSPHINE)NICKEL(II) BROMIDE
DIBROMOBIS(TRIPHENYLPHOSPHINE)NICKEL(II)
bis(triphenylphosphine)nickel(II) dibromide
Nickel(II)bromidebis(triphenylphosphine)
BIS(TRIPHENYLPHOSPHINE)NICKELBROMIDE
Nickel,dibromobis[triphenylphosphine]-
dibromonickel,triphenylphosphane
NiBr2(PPh3)2 bis(triphenylphosphine)nickel(II) bromide
Bis-(triphenylphosphino)-nickel bromide
Dibromobis(triphenylphosphine)nickel(Ⅱ)
Bis(triphenylphosphine)dibromonickel(II)
Nickel(II)bromide bis(triphenylphosphine)
TRA0005877

MDL Number

MFCD00015865

FAQ

What is Nickel(2+) bromide - triphenylphosphine (CAS: 14126-37-5)?

Nickel(2+) bromide - triphenylphosphine (CAS: 14126-37-5) is a complex compound with the formula [NiBr2(C6H5Ph)3]. It is a dark green solid known for its coordination chemistry and use in various applications.

What are the main uses of Nickel(2+) bromide - triphenylphosphine (CAS: 14126-37-5)?

Nickel(2+) bromide - triphenylphosphine is primarily used in catalysis, particularly in the hydrogenation of various substrates. It is also utilized in organic synthesis, as a ligand in coordination chemistry, and in some pharmaceutical applications.

Is Nickel(2+) bromide - triphenylphosphine (CAS: 14126-37-5) safe?

Nickel(2+) bromide - triphenylphosphine is generally safe under controlled conditions. However, it is flammable and toxic, so proper handling and protective measures, such as gloves and goggles, are necessary. Inhaling the fumes or coming into skin contact can be harmful.

How should Nickel(2+) bromide - triphenylphosphine (CAS: 14126-37-5) be stored?

Nickel(2+) bromide - triphenylphosphine should be stored in a cool, dry place away from direct sunlight and heat sources. It should be kept in a sealed container to prevent moisture absorption. Containers should be tightly sealed to maintain purity and stability.