Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (1:1)

Basic Information

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CAS Number

12354-85-7

Molecular Formula

C20H30Cl4Rh2

Molecular Weight

618.08 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Hydrocarbons

Basic Physical Properties

Melting Point

>300°C

Water Solubility

Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether

SMILES

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Cl[Rh]Cl.Cl[Rh]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C

InChI

InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4

InChIKey

AUBQNRPCZLEJIZ-UHFFFAOYSA-J

LogP

8.696900000000001

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Safety Information

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GHS Hazard Pictograms

H302

H312

H315

H319

H332

H335

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H332 Harmful if inhaled
Acute toxicity, inhalation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Stability

吸湿性

Synonyms & References

English

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium
Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE
DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER
BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM]
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer
Pentamethylcyclopentadienylrhodium(III) chloride dimer
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
PentamethylcyclopendienylRhodium dichloride dimer
Pentamethylcyclopentadienylrhodium(III) Dichloride Dimer
Pentamethylcyclopentadineyl Rhodium (III)
1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex
Bis(dichloro(pentamethylcyclopentadienyl)rhodium)
Bis(pentamethylcyclopentadienylrhodium dichloride)
Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer
Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium
Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer
PentaMethyl cyclopentadienyl RhodiuM dichloride diMer
Bis[(pentamethylcycl

MDL Number

MFCD00061552

Customs Code

28439000

FAQ

What is Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (CAS: 12354-85-7)?

Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (CAS: 12354-85-7) is a coordination compound featuring a rhodium(1+) ion coordinated with a 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide ligand and a chloride ion. It is a complex with a chemical formula of RhCl(C5Me5)2.

What are the main uses of Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (CAS: 12354-85-7)?

This compound is primarily used in catalytic research, particularly in homogeneous catalysis. It serves as a precursor in the synthesis of other rhodium complexes and in the development of new catalytic processes for organic reactions.

Is Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (CAS: 12354-85-7) safe?

While generally safe under normal handling conditions, this compound should be handled with caution due to its potential for skin and eye irritation. It is not classified as a carcinogen or a reproductive toxin. Adequate ventilation and protective gloves should be used during handling. Storage and disposal should follow standard laboratory safety protocols.

How should Dichlororhodium(1+) 1,2,3,4,5-pentamethyl-2,4-cyclopentadienide (CAS: 12354-85-7) be stored?

This compound should be stored in a dry, cool place away from direct sunlight and heat sources. It should be kept in a sealed, airtight container to prevent exposure to air and moisture. Handling should be minimized to avoid unnecessary exposure. It is important to store it in a fume hood or under a nitrogen atmosphere to protect the compound from oxidative degradation.