1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1)

Basic Information

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CAS Number

115826-95-4

Molecular Formula

C44H32Cl2P2Pd

Molecular Weight

800.01 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Boiling Point

724.3℃ at 760 mmHg

Flash Point

419°C

SMILES

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C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Pd]Cl

InChI

InChI=1S/C44H32P2.2ClH.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2

InChIKey

VDHAUMFISVWIRX-UHFFFAOYSA-L

LogP

10.55289999999999

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

800

Safety Information

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GHS Hazard Pictograms

H302

H312

H315

H319

H332

H335

Hazard Statement

H302 Harmful if swallowed
Acute toxicity, oral

H312 Harmful in contact with skin
Acute toxicity, dermal

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H332 Harmful if inhaled
Acute toxicity, inhalation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

Moisture Sensitive

Synonyms & References

English

MFCD00075254
dichloropalladium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)chloride
AT37026
(S)-BINAP-PdCl2
[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
AKOS015914422
[(R)-(+)-2,2/'-BIS(DIPHENYLPHOSPHINO)-1,1/'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
FT-0696080
FT-0696081
((S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium
SCHEMBL365531
((R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl)dichloropalladium...
[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride, 97%
PALLADIUM, [(1S)-[1,1'-BINAPHTHALENE]-2,2'-DIYLBIS[DIPHENYLPHOSPHINE-KAPPAP]]DICHLORO-, (SP-4-2)-
DICHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
F10282
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), 97%
(R)-(+)-(2,2-Bis(Diphenylphosphino)-1,1-binaphthyl)palladium(II)chloride
DICHLORO[2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
Dichloro[2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), 97%
Dichloro[(S)-()-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
115826-95-4
127593-28-6
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLADIUM(II) CHLORIDE
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%
[(R)-(+)-2,2’-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1-binaphthyl]palladium(II)
? Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
[(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) chloride

MDL Number

MFCD00075254

FAQ

What regulatory guidelines apply to 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4)?

1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4) is regulated by various guidelines depending on its intended use. Under REACH, it requires registration if manufactured or imported in quantities above thresholds. It falls under the GHS classification as a hazardous substance, with specific handling and labeling requirements. The FDA and EPA may also have specific regulations for its use and disposal in the United States. Always consult the latest regulatory documents for detailed information.

Are there alternatives to 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) in synthesis?

While 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4) is a specific reagent, alternatives include other palladium complexes such as dichlorobis(1,1'-binaphthyl-2,2'-diyl)amine. Isomers and analogs like 1,1'-binaphthalene-2,2'-diylbis(diphenylphosphine) may also be used depending on the desired properties. It is essential to evaluate these alternatives based on the specific reaction conditions and desired outcomes.

What is the market or research trend for 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4)?

The market for 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4) is driven by its applications in catalysts for organic synthesis, particularly in cross-coupling reactions. Recent research trends focus on the development of more efficient and environmentally friendly catalysts. The compound's demand is likely to increase as green chemistry principles are increasingly integrated into industrial processes.

How should waste containing 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4) be handled?

Waste containing 1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1) (CAS: 115826-95-4) should be collected in proper containers and labeled according to hazardous waste regulations. It is crucial to neutralize any residual dichloropalladium compounds before disposal. Waste should be incinerated or disposed of by a professional hazardous waste management facility. Follow local and international guidelines to ensure compliance with environmental protection standards.