Unveiling the multifunctional regulation effect of a glutamine additive for highly reversible Zn metal anodes

Literature Information

Publication Date 2023-12-07
DOI 10.1039/D3TA06593F
Impact Factor 12.732
Authors

Junyi Yin, Xiang Feng, Tianyi Cui, Jingzhe Chen, Fuxiang Li, Minghui Wang, Yonghong Cheng, Shujiang Ding, Xin Xu, Jianhua Wang


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Abstract

Uncontrollable side reactions and dendrites severely undermine the stability and reversibility of Zn anodes and remain significant challenges for aqueous zinc-ion batteries (AZIBs). Herein, it is demonstrated that glutamine (Gln) is a multifunctional electrolyte additive to enable highly stable and reversible Zn anodes. Theoretical and experimental results reveal that Gln has three functions: preferentially absorbing on the Zn anode and constructing a water-poor interface, enhancing the steric effect, and optimizing the solvation structures of Zn2+. Consequently, Zn//Zn batteries exhibited an impressive cycling durability and high cumulative capacity at 3 mA cm−2. Furthermore, Zn//Cu batteries also demonstrated a remarkably reversible stripping/deposition process accompanied by a notably high average coulombic efficiency of 99.6%. In addition, the fabricated Zn//NH4V4O10 batteries with Gln also yielded impressive cycle performances and capacity retention. Gln exhibits promising attributes as a cost-effective and versatile electrolyte additive to facilitate the stability and reversibility of AZIBs.

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Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
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