Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn12 core: a route to the controlled functionalisation of single-molecule magnets

Literature Information

Publication Date 2004-10-01
DOI 10.1039/B411320A
Impact Factor 6.222
Authors

Andrea Cornia, Antonio C. Fabretti, Laura Zobbi, Daniele Bonacchi, Andrea Caneschi, Guillaume Chastanet, Dante Gatteschi, Roberta Sessoli


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Abstract

A novel single-molecule magnet of the Mn12 family, [Mn12O12(O2CC6H5)8(L)4(H2O)4]·8CH2Cl2, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2−), which leads to selective occupation of axial binding sites.

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