Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn12 core: a route to the controlled functionalisation of single-molecule magnets
Literature Information
Andrea Cornia, Antonio C. Fabretti, Laura Zobbi, Daniele Bonacchi, Andrea Caneschi, Guillaume Chastanet, Dante Gatteschi, Roberta Sessoli
A novel single-molecule magnet of the Mn12 family, [Mn12O12(O2CC6H5)8(L)4(H2O)4]·8CH2Cl2, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2−), which leads to selective occupation of axial binding sites.
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![(2R)-2,7,8-Trimethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-6-chromanol structure (2R)-2,7,8-Trimethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-6-chromanol structure](https://static.chemtradehub.com/structs/54-/54-28-4-155c.webp)

![2,5-Furandione, dihydro-3-[3-(triethoxysilyl)propyl]- structure 2,5-Furandione, dihydro-3-[3-(triethoxysilyl)propyl]- structure](https://static.chemtradehub.com/structs/936/93642-68-3-3b4b.webp)

