Microwave-assisted synthesis of ZIF-9@xGO composites as cooperative electrocatalysts for electro-oxidation of benzyl alcohols coupled with H2 production
Literature Information
Sayantan Chongdar, Anirban Ghosh, Asim Bhaumik
Selective electrochemical oxidation of alcohols to their corresponding aldehydes or acids utilizing water as the oxygen source is not only considered a green and sustainable approach to synthesize value added chemicals but also economically demanding as the overall process is coupled with green H2 production. However, restricted production due to low current density and the use of expensive noble-metal-based electrocatalysts has limited its industrial viability. On the other hand microwave-assisted synthesis enables a rapid, economical and effective way to fabricate various advanced porous materials. In this regard, herein we report microwave assisted rapid synthesis of a metal–organic framework materials ZIF-9 nanocrystals and ZIF-9@xGO composites by varying the wt% of graphene oxide (GO). Remarkably, upon GO loading the current density increases significantly from 75 mA cm−2 to 204 mA cm−2 at 1.6 V vs. RHE in an alkaline solution with 0.1 M benzyl alcohol, thereby imparting direct impact towards benzoic acid yield (∼84%) and faradaic efficiency (∼88%) of the process. Moreover, the optimised electrocatalyst (i.e. ZIF-9@10GO) exhibits a H2 evolution rate of 273 mmol g−1 h−1 in the presence of benzyl alcohol. Our results indicate that in situ generated Co(OH)2/CoOOH hybrid species over the ZIF-9 surface plays an active role in this electrocatalysis. Additionally, this electrocatalytic system shows good functional group tolerance, exhibiting wide scope for different substrates with high faradaic efficiency.
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Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment











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