Organocatalytic activation of hydrogen peroxide: towards green and sustainable oxidations

Literature Information

Publication Date 2023-12-18
DOI 10.1039/D3SC05618J
Impact Factor 9.825
Authors

Efthymios T. Poursaitidis, Petros L. Gkizis, Ierasia Triandafillidi, Christoforos G. Kokotos


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Abstract

The advent of organocatalysis provided an additional option in every researcher's arsenal, towards the development of elegant and sustainable protocols for various organic transformations. Oxidation reactions are considered to be key in organic synthesis since oxygenated functionalities appear in many natural products. Hydrogen peroxide is categorized as a green oxidant, since its only by-product is water, offering novel opportunities for the development of green and sustainable protocols. In this review article, we intend to present recent developments in the field of the organocatalytic activation of hydrogen peroxide, providing useful insight into the applied oxidative protocols. At the same time, we will present some interesting mechanistic studies, providing information on the oxygen transfer processes.

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