Lewis acid catalysed polymerisation of cyclopentenone
Literature Information
Publication Date
2023-12-02
DOI
10.1039/D3SC05186B
Impact Factor
9.825
Authors
Deepamali Dissanayake, Alysia Draper, Neelofur Jaunnoo, Joris J. Haven, Craig Forsyth, Alasdair I. McKay, Tanja Junkers, Dragoslav Vidović
View Original
Abstract
A modest structural change of a β-diketiminate-supported aluminium complex leads to dramatic differences in the reactivity towards cyclopentenone. While the bulkier complex efficiently executes Diels Alder transformations the smaller analogue performs unique polymerisation of this substrate. This observation appears to be unprecedented in the chemistry of Lewis acids and cyclic dienophiles as it represents a unique way to polymerise a functionalised olefin.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
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Recommended Compounds
N,N-Diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide
CAS Number:
325142-99-2
Molecular Formula:
C17H26BNO3
![1-[3-(4-Morpholinylsulfonyl)phenyl]methanamine structure](https://static.chemtradehub.com/structs/933/933989-32-3-51af.webp "1-[3-(4-Morpholinylsulfonyl)phenyl]methanamine structure")
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