Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons
Literature Information
Biswajit Kalita, Angus A. Lamar, Kenneth M. Nicholas
Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2–H2O-catalyzed reaction with PhINTs; saturated adamantane is aminosulfonated at the tertiary C–H bond.
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![1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure 1,2-Diphenyl-4-[2-(phenylsulfinyl)ethyl]-3,5-pyrazolidinedione structure](https://static.chemtradehub.com/structs/57-/57-96-5-efcc.webp)



