Cyclometallated platinum(ii) complexes incorporating ethynyl–flavoneligands: switching between triplet and singlet emission induced by selective binding of Pb2+ ions
Literature Information
Pierre-Henri Lanoë, Jean-Luc Fillaut, Loïc Toupet, J. A. Gareth Williams, Hubert Le Bozec, Véronique Guerchais
Platinum–ethynylflavone complexes featuring various polyether arms display 3IL phosphorescence associated with the appended flavone perturbed by the platinum centre (τ ∼20 μs), but switch dramatically to flavone-localised 1IL fluorescence (τ ∼ 2 ns) upon selective binding of Pb2+.
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