Advances in CO2 activation by frustrated Lewis pairs: from stoichiometric to catalytic reactions
Literature Information
Publication Date
2023-11-09
DOI
10.1039/D3SC03907B
Impact Factor
9.825
Authors
Yara van Ingen, Tribani Boruah, Adam McLauchlan, Thomas Wirth, Rebecca L. Melen
View Original
Abstract
The rise of CO2 concentrations in the environment due to anthropogenic activities results in global warming and threatens the future of humanity and biodiversity. To address excessive CO2 emissions and its effects on climate change, efforts towards CO2 capture and conversion into value adduct products such as methane, methanol, acetic acid, and carbonates have grown. Frustrated Lewis pairs (FLPs) can activate small molecules, including CO2 and convert it into value added products. This review covers recent progress and mechanistic insights into intra- and inter-molecular FLPs comprised of varying Lewis acids and bases (from groups 13, 14, 15 of the periodic table as well as transition metals) that activate CO2 in stoichiometric and catalytic fashion towards reduced products.
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Source Journal
Chemical Science
CiteScore:
14.4
Self-citation Rate:
3.9%
Articles per Year:
1413
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